If you want a full episode-by-episode index (titles, original air dates, brief synopses), I can produce a complete season-by-season list. Which format do you prefer: one-line episode index, detailed synopses, or a printable table with air dates?
A "detailed paper" on the franchise also involves indexing the core elements that defined the "U.N.C.L.E." (United Network Command for Law and Enforcement) and its rival "THRUSH". : Index Of The Man From Uncle